BCH 4024 Chapter Notes - Chapter 28-32: Nadh Dehydrogenase, Intermembrane Space, Atp Synthase

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28: oxidative phosphorylation- synthesis of atp from the free energy made available through the flow of electrons, from glucose oxidation- 12 pairs of electrons are transferred to nad and fad (eventually reduce o2 to h2o) Inner membrane- impermeable to most things including h+ (need pumps: respiratory electron carriers, adp-atp translocase, atp synthase, and other membrane transporters, cristae- increased surface area increases amount of energy supplied. N is the number of electrons transfered: general reaction in which oxygen is reduced to water in the electron transport system, o2 + nadh + h+ H2 o + nad: cytochromes b,c,c1, a, and a3 are proteins containing heme (protoporphyrin) rings that have fe bound to them. The iron undergoes reversible oxidation and reduction: ubiquinone(coenzyme q)- lipid in the mitochondrial membrane that undergoes oxidation and reduction of one or two protons or electrons, moving freely within the membrane.

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