CHM 145 Lecture 13: 2/14/17

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Polyprotic acids: monoprotic acids have only one ionizable hydrogen atom per molecule, polyprotic acids have two or more ionizable hydrogen atoms per molecule. Diprotic = 2 h+ ions, triprotic = 3 h+ ions example: carbonic acid h2co3 (aq) + h2o(l) <=> h3o+ (aq) + Hco3 - (aq) ka1 = 4. 3 x 10 7 hco3 (aq) + h2o(l) <=> h3o+ (aq) + co3 2 (aq) ka2 = 4. 7 x 10 11. What is the ph of a 0. 500 m solution of h2so4 (ka1 >>1, and ka2 = 1. 2 x. Step 1 100% r hso4 (aq) + h2o(l) <==> h3o+ (aq) + so4 2 (aq) i. 0. 500 -- 0. 500 0 c x -- +x +x e 0. 500 x -- 0. 500 + x x ka = [h3o+ Calculate the ph of 0. 100 m carbonic acid, h2co3 , solution (ka1 = 4. 3 x 10-7 and ka2 = 4. 7 x.

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