CHEM 250- Final Exam Guide - Comprehensive Notes for the exam ( 404 pages long!)

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30 Nov 2017
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16. 1 monobromination of toluene gives a mixture of three bromotoluene products. Solution: o-xylene: 2. m-xylene: 3 p xylene: 1. 16. 3 when benzene is treated with d2so4, deuterium slowly replaces all six hydrogens in the aromatic ring. 16. 5 what is the major monosubstitution product from the friedel-crafts reaction of benzene with. 16. 6 identify the carboxylic acid chloride that might be used in a friedel-crafts acylation reaction to prepare each of the following acylbezenes: 16. 7 write resonance structures for nitrobenzene to show the electron-withdrawing resonance effect of the nitro group. 16. 8 write resonance structures for chlorobenzene to show the electron-donating resonance effect of the chloro group. 16. 9 predict the major products of the following reactions: (a) mononitration of bromobenzene (b) monobromination of nitrobenzene (c) monochlorination of phenol (d) monobromination of aniline. The reaction system should not have h+, otherwise the amino group will transfer to be a meta orientation group.

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