BIOC 1430 Lecture Notes - Lecture 7: Carboxylic Acid, Hydrogen Bond, Organic Compound

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Examples: reaction with alcohol, carboxylic acid reacts with alcohols in the presence of acid catalyst to produce esters, this reaction is called esterification, involves removal of water molecules, it is a condensation reaction. Isomerism for carboxylic acids and esters: constitutional isomers occur because of different carbon skeletons and different positions for the functional group, carboxylic acid skeletal isomers: (examples: pentanoic acid and 2-methylbutanoic acid) Examples: ester positional isomers: (examples: methyl propanoate and ethyl ethanoate) Examples: functional group isomers: these are carboxylic acids and esters with the same number of carbon atoms. (examples: pentanoic acid and ethyl propanoate; molecular formula c5h10o2. Examples: saponification, esters can also be hydrolyzed when heated in an aqueous solution of strong base (koh or (basic hydrolysis) Naoh): produces an alcohol and potassium or sodium salts of the carboxylic acid, reaction is known as saponification, saponification of fats and oils produces soap. Sulfur analogs of esters: just as alcohols react with carboxylic acid to produce esters.

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