BIO 1130 Lecture Notes - Lecture 13: Dimensionless Quantity, Dynamic Equilibrium, Chemical Equilibrium

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BIO 1130 Full Course Notes
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BIO 1130 Full Course Notes
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Dynamic equilibrium: so far, we have considered reactions that go in one direction, equilibrium: two opposing processes taking place at equal rates no net reaction. N2o4(g) 2no2(g) equals the rate of dimerization: 2no2(g) n2o4(g). is dynamic equilibrium: the equilibrium is dynamic because the reaction has not stopped: the opposing rates are equal. The concept of equilibrium: for an equilibrium, we write. , which represents the equilibrium constant: keq is based on the activities of reactants and products activities are dimensionless quantities and give dimensionless keq. In ideal conditions: for solutions, the activity is the numerical value of the molarity m, for gases activity is represented by the pressure - p, for pure substance as a solid or liquid the activity is 1. Properties of equilibrium constants: keq is related to the stoichiometry of the balanced net reaction, keq applies only at equilibrium, keq is independent of initial conditions. If two chemical equations are added, their equilibrium constants are multiplied:

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