CHEM 2410 Lecture Notes - Lecture 4: Mechanistic Organic Photochemistry

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As you have experienced through recommended exercises, certain equations that are not indexed in the textbook may be needed in your calculations. You will be responsible to know it in those cases. A good example is (cid:41)(cid:82)(cid:85)(cid:3)(cid:85)(cid:72)(cid:68)(cid:70)(cid:87)(cid:76)(cid:82)(cid:81)(cid:86)(cid:3)(cid:82)(cid:73)(cid:3)(cid:87)(cid:75)(cid:72)(cid:3)(cid:87)(cid:92)(cid:83)(cid:72)(cid:3)(cid:36)(cid:3)(cid:14)(cid:3)(cid:37)(cid:3)(cid:314)(cid:3)(cid:51)(cid:3)(cid:76)(cid:81)(cid:3)(cid:87)(cid:75)(cid:72)(cid:3)(cid:74)(cid:68)(cid:86)(cid:3) phase, ea (cid:32)(cid:3)(cid:168) h + 2rt. For these reactions in solution, ea = (cid:168) h + rt. There will be 5 calculations in part 2 and 5 (out of 6) questions in part 3. Office hour: monday (april 22) 9 am to 5 pm. (cid:32)(cid:47) 0 m v (cid:79) v (cid:14)(cid:14) (cid:14) (cid:79) (cid:16)(cid:16) ka. E-af(cid:536) jc = j0e-af(cid:536) j = j0(e(1-a)(cid:1861)f(cid:536) ) (cid:1861) = e" e, ja = j0e(1-a)f(cid:536) j = j0f(cid:536) ln(j) = ln(j0) + (1-a)f(cid:536) ln(-j) = ln(j0) af(cid:536) jlim = zfj = zfdc/ (cid:303) jlim = crt(cid:540)/(zf(cid:303)) ; (cid:513)m = (cid:302)(cid:513)0m k k eq (cid:32) 21/ (cid:183) (cid:184)(cid:184) (cid:185) (cid:47)(cid:32)(cid:47) (cid:189) (cid:176) (cid:190) 1(cid:32) v (cid:173) (cid:167) (cid:176) (cid:168)(cid:168) (cid:174) (cid:169) (cid:176)(cid:175) constant m (cid:32)(cid:47) eak a.

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