CAS BI 105 Lecture Notes - Lecture 13: Exergonic Reaction, Chemical Bond, Chemical Reaction

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raspberryserval680

30 Apr 2018

School

Boston University

Department

Biology

Course

CAS BI 105

Professor

Elizabeth Ann Stanford

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Energy and Enzymes

Metabolism

•The sum of all chemical reactions in one organism

•Chemical reactions - using energy to break a bond or gaining energy when a bond is broken

Energy

•The capacity to do work

•What is work?

•Chemical Work: making and breaking chemical bonds, building and breaking molecules

•Kinetic Work: move ions, molecules, large things in/out of the cell or the entire cell across a

surface/tissue

Types of Energy

•Kinetic Energy: the energy of motion

•ex: moving sodium across the membrane, down its concentration gradient

•ex: rolling a ball down a hill

•Potential Energy: stored energy

•An object wants to move and will move if allowed (the POTENTIAL to move)

•ex: disequilibrium of sodium ready to move down its concentrating radiant

•ex: ball poised at the top of the hill, ready to roll down

•Thermal Energy: heat

•Reactions often lose energy in the form of heat

•Chemical Energy: potential energy in food/storage molecules

•Fewer chemical reactions - body temperature drops

•More chemical reactions - body temperature rises

Energy Transformations

•Constant changes of energy from one form to another

•ex: chemical energy (wood) —> thermal energy (fire)

•Thermodynamics: the study of energy transformations

•2 laws of thermodynamics

•1st law - energy can neither be created nor destroyed, only converted from one form to another

•Exergonic Reaction - energy released when you break a bond

•Need to capture energy in order to use in ADP-ATP conversion

•Endergonic Reaction - energy required to make a bond

•Where do we get energy for these reactions?

•By coupling an endergonic and exergonic reaction at the same place & time (one energy

fuels the other)

•By storing energy as potential energy in electrons carried on nucleotides (ex: NADH/

FADH2)

•Energy transfer molecules carry the energy until it can be used in the ADP-ATP

conversion

•2nd law - every energy transfer of transformation increases entropy, thus the entropy of the

universe is always increasing

•entropy = disorder/chaos = energy lost when trying to convert from one form to another (heat

lost)

•*entropy results in unusable energy

•ex: entropy increases as more heat and small molecules are released

Intermediates

•Sometimes a reaction is not as simple as A + B —> C

•If there are many sets involved the molecules are known as intermediates

•ex: A + B —> C —> D —> E

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Energy in a Reaction

•Making a chemical bond takes energy - endogenic

•Breaking a chemical bond releases energy - exergonic

•constantly cycles back and forth between ATP and ADP states

Metabolism

•All chemical reactions in an organism

•Energy is extracted from nutrients

•Synthesize or breakdown of molecules

•Catabolism: reactions that release energy by breaking down molecules

•Anabolism: reactions that required energy to build molecules

•Energy used and taken in

Cellular Reactions

•Often reversible

•Different enzymes are required for each direction/new level of control

•Will be either catabolic or anabolic

•ex: A + B <—> C + D

•Often a reaction is slow & impossible to complete without help

•Activation Energy - the energy needed to bring molecules close together/align them in a certain

arrangement

•This is the typical cause of resistance to a reaction

•The energy needed to start a reaction

•Enzymes try to reduce activation energy and make reactions easier

Enzymes

•Some reactions occur slowly on their own

•Enzymes: proteins that catalyze (speed up) reactions

•Substrate: the molecule that the enzyme acts on

•*All ligands are substrates, not all substrates are ligands

•Co-factor: another binding partner that may control the enzyme

•Control - to maintain homeostasis we must control enzyme activity

•Can keep the enzyme inactive, activate when needed (cofactors)

•Inhibit enzyme when not needed

•ex: CO2 + H2O —> Carbonic Acid

•Reaction Rate = 1 molecule/100 seconds

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Document Summary

Metabolism: the sum of all chemical reactions in one organism, chemical reactions - using energy to break a bond or gaining energy when a bond is broken. Energy: the capacity to do work, what is work, chemical work: making and breaking chemical bonds, building and breaking molecules, kinetic work: move ions, molecules, large things in/out of the cell or the entire cell across a surface/tissue. Intermediates: sometimes a reaction is not as simple as a + b > c, if there are many sets involved the molecules are known as intermediates, ex: a + b > c > d > e. Energy in a reaction: making a chemical bond takes energy - endogenic, breaking a chemical bond releases energy - exergonic, constantly cycles back and forth between atp and adp states. Enzyme binds substrate and forms an enzyme-substrate complex: 2. Chemical reaction occurs - enzyme is not bound to product anymore: 3.

Related Questions

Question 1

Plasma membranes are selectively permeable. This means that

	A.	glucose cannot enter the cell.
	B.	the plasma membrane allows some substances to enter or leave a cell more easily than others.
	C.	plasma membranes must be very thick.

Question 2

Oxygen molecules O₂ crosse a plasma membrane by

	A.	passive transport
	B.	osmosis
	C.	active transport

Question 3

Facilitated diffusion across a biological membrane requires ________ and moves a substance ________ its concentration gradient.

		A. energy and channel proteins; against (up)
		B. transport proteins that make channels ; down
		C. energy ; down

Question 4

When two aqueous solutions that differ in solute concentration are placed on either side of a semipermeable membrane and osmosis is allowed to take place, the water will

		A. move to the side with lower water concentration
	B.	move to the side with higher water concentration
	C.	move to the side with lower solute concentration

Question 5

Kinetic energy differs from chemical energy in that

	A.	chemical energy is a particular form of kinetic energy.
	B.	kinetic energy is the energy of a moving object, whereas chemical energy is the potential energy of molecules.
	C.	kinetic energy is stored energy that has the potential to do work, and chemical energy is the energy of movement.

Question 6

When a cell uses chemical energy to perform work, it uses the energy released from a(n) ________ reaction to drive a(n) ________ reaction.

	A.	exergonic; endergonic
	B.	endergonic; exergonic
	C.	spontaneous; exergonic

Question 7

When an enzyme catalyzes a reaction

		A. it raises the activation energy of the reaction.
		B. it lowers the activation energy of the reaction.
		C. it is used once and discarded.

Question 8

Which of the following statements regarding enzyme function is false?

		A. An enzyme's function depends on its three-dimensional shape.
		B. Enzymes are very specific for their substrates.
		C. Enzymes are used up when they catalyze a chemical reaction so must be synthesized for each new chemical reaction

Question 1 When energy changes from one form to another, some of the energy that can be used to do work is always lost. The loss of this energy is mostly in the form of _________.
a. heat
b. potential energy
c. kinetic energy
d. light energy
e. mechanical energy

Question 2 Which of the following is exergonic?
a. binding fatty acids and glycerol molecules together to form lipids
b. building proteins from amino acids
c. binding sugars molecules together to form glycogen
d. breaking bonds in starch to release glucose
e. adding a phosphate group to ADP to form ATP

Question 3 The first law of thermodynamics states that:
a. energy can neither be created nor destroyed.
b. the universe is increasing in entropy.
c. all living organisms must eat to derive energy.
d. energy is required to bring molecules into a cell against a concentration gradient.
e. in energy-yielding reactions, matter goes from a more-ordered to a less-ordered state.

Question 4 Which of the following is true of energy?
a. It can be transferred from one form to another with 100 percent efficiency.
b. It can be created.
c. It can be stored in chemical bonds.
d. It can never be stored.
e. It can be released by forming chemical bonds.

Question 5 Metabolism is:
a. the sum of all the energy a cell uses.
b. the sum of all the vitamins a cell contains.
c. the sum of all the enzymes a cell contains.
d. the sum of all the chemical reactions that an organism carries out.
e. the sum of all the ATP a cell contains.

Question 6 Entropy is the measure of ________ in a system.
a. disorder
b. order
c. energy
d. work
e. heat

Question 7 What percentage of the energy stored in glucose are humans cells able to use to do useful work?
a. 37%
b. 100%
c. 15%
d. 52%
e. 48%

Question 8 What is activation energy?
a. the energy gained by living things, allowing them to remain active
b. the energy produced by the breakdown of ATP to ADP.
c. the energy required to initiate or begin a chemical reaction
d. the energy created by enzymes during exergonic reactions
e. the energy lost by living things in the form of heat

Question 9 Which of the following is true of allosteric enzymes?
a. Their activity can be reduced when the product binds the enzyme.
b. Their activity can be reduced when a coenzyme binds to them.
c. Their activity can be reduced when the substrate binds the enzyme.
d. Their activity can be increased when the product binds the enzyme.

Question 10 Which of the following is a true statement about enzymes?
a. They are made of proteins.
b. They are altered by the reactions they catalyze.
c. They increase the energy of activation of chemical reactions.
d. All of the above are true.
e. None of the above is true.

Question 11 What is the energy currency of cells?
a. ADP
b. enzymes
c. glucose
d. vitamins
e. ATP

Question 12 Kinetic energy is ____________, while potential energy is _____________.
a. stored energy; energy that is being used
b. stored energy; energy that can't be used
c. energy that is being used; stored energy
d. energy that can't be used; stored energy

Question 13 The energy released during ________ reactions can be used to drive ________ reactions, and this is called ________ reactions.
a. exergonic; endergonic; coupled
b. endergonic; exergonic; coupled
c. exergonic; endergonic; mutually dependent
d. coupled; mutually dependent; independent
e. endergonic; exergonic; mutually dependent

Question 14 ADP + P + Energy --> ATP Which of the following is a true statement about the chemical reaction above?
a. This is a coupled reaction.
b. This is an exergonic reaction.
c. The product of the reaction contains more energy than that of all of the reactants combined.
d. This is an endergonic reaction.
e. This is an example of a catabolic reaction.

greychimpanzee211

1.When something appears blue, it is absorbing all colors except__________.

yellow

blue

red

green

orange

2.During heavy exercise, lactic acid can build up in ourmuscles. Why? How does this resemble the metabolism of bacteria andyeast?

lactic acid is results from insufficient oxygen during sugarmetabolism; it is fermentation

lactic acid accumulates when we are dehydrated; bacteria andyeast use the same pathway

lactic acid is built up from carbon dioxide; bacteria and yeaststore energy in this way

3.Why must a cell keep a similar concentration of dissolvedsubstances with the fluid surrounding them?

to avoid dilution of potential energy

to avoid osmotic imbalance and rapid gain or loss of water

to maintain the correct amount of dehydration and hydrolysis

4.What is entropy?

the amount of energy in a system

the amount of disorganization

the amount of organization

5.Burning a log is the reverse reaction found in photosynthesis.What products would be formed in burning a log?

carbon dioxide and water

glucose and oxygen

oxygen and carbon dioxide

oxygen and water

6.The main reason that cellular respiration needs to occur stepby step instead of a single, big reaction is

cells don't store enough oxygen

too much energy would be released for the cell to harness

cells don't have many mitochondria.

cells produce the enzymes needed for cellular respiration veryslowly

7.Enzymes are catalysts because they operate to:

raise activation energy

lower activation energy

supply activation energy

supply the reactants

8.When ATP powers a reaction it becomes ADP. The ADP

can reform ATP by an exergonic reaction

is a waste product for lysosomal breakdown

can reform ATP by an endergonic reaction

can reform ATP by an oxidation reaction

can reform ATP by an equilibrium reaction

9.The energy source that drives photosynthesis is

water

glucose

carbon dioxide

oxygen

sunlight

10. What is the process by which enzymes regulate their ownactivity?

osmosis

self-propulsion

feedback inhibition

11.Coupled reactions are reactions in which a

endergonic reaction drives a spontaneous reaction

exergonic reaction drives a spontaneous reaction

endergonic reaction drives an exergonic reaction

exergonic reaction drives an endergonic reaction

12.How is water used in photosynthesis?

as a substrate for ATP synthase

as an electron donor

to combine with ADP forming ATP

as an electron acceptor

13.Why are the âDark Reactionsâ of photosynthesis referred to asâDarkâ?

they do not require light

they can only occur at night

they generate excess sugar and the leaves turn brown

14.What is the difference between potential and kineticenergy?

potential is stored, kinetic is being used

potential is being used, kinetic is ready to be used

potential is negative, kinetic is positive

15.The products of cellular respiration are

carbon dioxide, water, and ATP

glucose, water, and ATP

glucose, carbon dioxide, and ATP

oxygen, ATP, and water

carbon dioxide, glucose, and water

16.All of the following are correct about energy except:

The biological world gets its energy from the sun.

Chemical bonds store potential energy.

A boulder perched on a hill has kinetic energy.

Energy is defined as the ability to do work.

All forms of energy can be converted to heat.

17.What is needed for the end product of glycolysis, pyruvate,to enter the citric acid cycle?

More glucose for energy

ATP

Oxygen

Carbon dioxide

18.The enzyme that forms a transmembrane channel in mitochondriaand phosphorylates ADP

a carrier protein

ATP synthase

acetyl CoA

19.Fermentation is most common in

plants

microorganisms

animals

20.During adsorption of sunlight by photosystems, H+ ions aregenerated. Where do they come from? What are they used for?

from the breakdown of sugar; they help form water

water; they help form sugar

from carbon dioxide; they help dissolve NaCl

21.Glycolysis

does not use oxygen

uses oxygen

uses carbon dioxide

22.Photosynthesis is

not dependent on chlorophyll

a process that produces glucose and oxygen

a process that produces water and carbon dioxide

23.Breakdown of glucose generates many ATP molecules, each ofwhich can be used independently. Why is ATP ideally suited to powerbiological reactions?

ATP has many hydrogen bonds

ATP has enough energy to power one biological reaction

ATP readily dissolves in water

24.Objects that are not actively moving but have the capacity todo so are said to possess:

kinetic energy

entropy

potential energy

living energy

25.The first stage of cellular respiration, called ___________,takes place in the cytoplasm of the cell and needs no oxygen.

photorespiration

citric acid cycle

glycolysis

oxidation

26.Diffusion

requires energy

utilizes proteins to move molecules across a membrane

moves molecules against a concentration gradient

does not require energy

cannot occur without a membrane present

27.What is the name of the molecule on which an enzymeworks?

substrate

monomer

polymer

28.ATP contains

phenylalanine

two phosphate groups

three nitrate groups

three phosphate groups

29.How does chlorophyll function in photosynthesis?

by absorbing carbon dioxide

by absorbing the sun's energy

by absorbing water

30.Objects that are moving are said to possess:

living energy

potential energy

entropy

kinetic energy

31.The respiration pathway that evolved first is probably

glycolysis

aerobic respiration

citric acid cycle

32.The energy source for the process of photosynthesis is

oxygen

sunlight

carbon dioxide

chlorophyll

glucose

33.Burning wood generates heat and light. What type of reactionis this?

exergonic

kinetic energy

endergonic

potential energy

equilibrium

34.What is meant by a âcoupled reactionâ in terms of energy?

many poymers are built simultaneously

energy released by one reactions powers another reaction

some reactions occur in the same organelle

35.The First Law of Thermodynamics states:

energy is constantly being created by entropy events

energy can be changed from one form to another, but cannot becreated or destroyed

energy can be used and then destroyed because of entropy'sactions on it

energy can be destroyed while it is producing entropy

36.How do we dispose of the carbon derived from the glucose thatis metabolized during respiration?

by breathing out

via our urine

it is broken down in lysosomes

37.Both plant and animal cells have mitochondria because theyboth

carry on respiration

carry on photosynthesis.

require water

38.What is Activation Energy?

the energy needed to initiate a reaction

the energy that transports water into cells

potential energy

39.If you put a plant in a chamber and shine a light on it

oxygen will decrease and carbon dioxide will increase

oxygen will increase and carbon dioxide will decrease

oxygen and carbon dioxide will increase

oxygen and carbon dioxide will decrease

40.What are the inputs and the output molecules for the overallphotosynthetic process?

input sugar and oxygen; output carbon dioxide and water

input oxygen and water; output sugar and carbon dioxide

input carbon dioxide and water;output sugar and oxygen

41.What kind of reaction is photosynthesis?

endergonic

kinetic energy

exergonic

potential energy

equilibrium

42.In the process of glycolysis, glucose is cleaved into a pairof three-carbon molecules called

lactate

pyruvate

acetyl CoA

ATP

alcohol

43.Entropy is

order

disorder

complexity

Both order and disorder are correct

Both complexity and disorder are correct

44.Glycolysis takes place in the _____________ and the citricacid cycle and electron transport chain take place in the___________.

cytoplasm; endoplasmic reticulum

mitochondria, chloroplast

mitochondria; cytoplasm

cytoplasm; mitochondria

45.The organelle that carries out photosynthesis in plants isthe

mitochondria

chloroplast

ribosome

chlorophylllysosome

46.The energy to power the Calvin cycle comes from

cellular respiration

oxygen

the light reactions of photosynthesis

47.Which of the following can be broken down into intermediateproducts that enter cellular respiration?

Proteins

Lipids

Carbohydrates

All of these.

48.When cellular product levels get too high, the responsibleenzyme is inhibited. This is an example of

promotion

denaturation

equilibrium

a coenzyme

feedback inhibition

49.How is respiration the opposite of photosynthesis?

respiration breaks sugar down to carbon dioxide; photosynthesisbuilds sugar from carbon dioxide

respiration builds sugar from carbon dioxide; photosynthesisbreaks sugar down to carbon dioxide

respiration requires energy input; photosynthesis gives offexcess energy

50.The molecule that absorbs sunlight for photosynthesis is

oxygen

carbon dioxide

chlorophyll

glucose

sunlight

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CAS BI 105 Lecture Notes - Lecture 13: Exergonic Reaction, Chemical Bond, Chemical Reaction

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