OCS 1005 Lecture : Lindau First Notes

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10/10/11
1. Atoms are composed of two different components
a. Positively charged nucleus
b. Negatively charged electron cloud surrounding the nucleus
2. Nucleus is composed of protons (positively charged) and neutrons (neutral)
a. Protons weigh ~ 1,836 times the mass of an electron and neutrons equal
~ the mass of a proton
b. Since atom is neutral with respect to electrical charges the number of
protons is equal to the number of electrons
3. Number of nuclear protons = Z = atomic number; different atomic (Z) number
for each element
4. Total number of neutrons = N
5. Mass number = A = N + Z
6. Specific nuclear species is called a nuclide
a. Aka isotope (used as tracers)
b. 1500 nuclides even though there are only 100-110 elements; obviously
each element can have more than one nuclide
c. same number of protons but different number of neutrons
i. can’t change protons because z number cannot change
d. 2 types of isotopes
i. stable isotopes ~ 280 isotopes
ii. radioactive isotopes ~ 1220 isotopes
1. neutron to proton ratio is unstable so they undergo a
nuclear change
2. emit particles or electromagnetic radiation to get back to
being stable
3. T1/2 = half life = amount of time for half of the radioactive
atoms to disappear
7. The most abundant atom in the universe is hydrogen and isotopes of hydrogen
a. Protium = hydrogen 1 isotope
i. One proton, one electron, no neutron = mass of one
ii. Stable isotope
iii. Natural abundance of 99.985%
b. Deuterium = hydrogen 2 isotope
i. One proton, one electron, one neutron = mass of 2
ii. Stable isotope
iii. Natural abundance of .015%
c. Tritium = hydrogen 3 isotope
i. One proton, one electron, two neutrons = mass of 3
ii. Unstable isotope (radioactive) will decompose into helium
because the proton to neutron ratio was off
iii. T1/2 = 12.3 years
8. Carbon has 12-14 isotopes but only use a few as tracers
a. Carbon 12
i. 6 protons, 6 electrons, 6 neutrons
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ii. Stable isotope
iii. Natural abundance of 98.89%
b. Carbon 13
i. 6 protons, 6 electrons, 7 neutrons
ii. Stable isotope
iii. Natural abundance of 1.11%
c. Carbon 14
i. 6 protons, 6 electrons, 8 neutrons
ii. Unstable isotope (radioactive) will decay to carbon-13
iii. T1/2 = 5,730 years
9. Nitrogen has a lot of isotopes but use only a few as tracers
a. Nitrogen 14
i. 7 protons, 7 electrons, 7 neutrons
ii. Stable isotope
iii. Natural abundance of 99.63%
b. Nitrogen 15
i. 7 protons, 7 electrons, 8 neutrons
ii. Stable isotope
iii. Natural abundance of .37%
c. Nitrogen 13
i. 7 protons, 7 electrons, 6 neutrons
ii. Unstable isotope (radioactive) will decay to carbon-13
iii. T1/2= 10 minutes
10. Oxygen is ½ of earth’s crust by weight (mass)
a. Oxygen 16
i. 8 protons, 8 electrons, 8 neutrons
ii. Stable isotope
iii. Natural abundance = 99.759%
b. Oxygen 17
i. 8 protons, 8 electrons, 9 neutrons
ii. Stable isotope
iii. Natural abundance of .037%
c. Oxygen 18
i. 8 protons, 8 electrons, 10 neutrons
ii. Stable isotope
iii. Natural abundance of .204%
d. Oxygen 15
i. 8 protons, 8 electrons, 7 neutrons
ii. Unstable isotope (radioactive) will decay to nitrogen-15
iii. T1/2 = 124 seconds
11. Sulfur must have it’s natural isotopic abundance altered in order to be used as a
tracer or it must have a distinct signature
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12. Isotope tracer applicatins
a. Environmental pollution to ocean, atmosphere, and coastal waters
i. use stable isotopes such as carbon 13/carbon 12, nitrogen
15/nitrogen 14, and sulfur 34/sulfur 32
1. indicators of manmade pollution
b. Water resources
i. Use stable isotopes oxygen 18/oxygen 16 and hydrogen
2/hydrogen 1
ii. Monitor surface water runoff into rivers and oceans
iii. Look at mixing rate and source identification of different water
masses
c. Radioactive dating
i. Use radioactive isotope carbon 14
ii. Age dates dead organic compound in ocean and inorganic
compounds that have carbon in them
iii. Look at past marine environments
d. Monitor carbon cycles or food chains in oceans of marine organisms
i. Use carbon 13/carbon 12 ratios
ii. Investigate trophic levels
13. Water molecule
a. Made of two hydrogen atoms and one oxygen atom
b. Molecular weight depends on which isotopes are used
i. Main hydrogen isotope has mass of 1 and mass of main oxygen is
16 so the most common molecular weight is 18g
ii. If using deuterium and oxygen 18, the molecular weight is 22g
c. French chemist, Lavoisier, was the first to figure out that water was
composed of two gases- hydrogen and oxygen (in 1783)
i. 1794 was executed by French government on the guillotine
d. Water is a compound and a molecule
i. Compound = substance that contains 2 or more elements in a fixed
ratio
1. H20, CO2, Fe2O3, C6H12O6
ii. Molecules = groups of atoms held together by a chemical bond
e. Formed when electrons are shared between two hydrogen atoms and one
oxygen atom in a covalent bond
i. Covalent bonds connect atoms by sharing the energy of paired
electrons
f. Each molecule has a net positive end and a net negative end; positive is
hydrogen and negative is oxygen
i. Net positive end attracts negative particles and net negative end
attracts positive particles
ii. Can attract other water molecules because of different charges
g. Polar nature explains why water can dissolve so many elements or
compounds
i. Known as universal solvent!
ii. Polar because of angular arrangement
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