01:160:308 Lecture Notes - Lecture 25: Mutarotation, Decarboxylation, Formaldehyde

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17 Apr 2018
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Chapter 25 carbohydrates: monosachharides, cyclic structures of monosachharides, reactions of monosachharides, disachharides and polysachharides. Carbohydrates have general formula (ch2o)n. they are classified into four groups: monosaccharide: simple sugars that cannot be converted into a smaller group. D-glucose: disaccharides: hydrolyzed into two sugars, can be same or different sucrose: hydrolyzes into glucose and fructose, oligosaccharides: give 3-10 sugar molecules at hydrolysis, polysaccharides: contain more than 10 monomers. Monosachharides: the monosaccharides are the simplest of the carbohydrates, since they contain only one polyhydroxy aldehyde or ketone unit, monosaccharides are classified according to the number of carbon atoms they contain: 6 triose tetrose pentose hexose: the presence of an aldehyde is indicated by the prefix aldo- and a ketone by the prefix keto-. Page 2: there is no correlation between d and l with (+) and (-) optical rotation. Optical rotation is an experimental fact: for all naturally occurring monosaccharides, the only stereo center that differs is the last chiral center.

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