CHE 202 Lecture Notes - Lecture 22: Cyclohexane, Cyclohexane Conformation, Cyclopentane

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17130 , 32. 36 chapter 7 : cyclohexane cyclopentane cyclobutane cyclopropane planar puckered angle. X eclipsing chair conformation (no angle itorsonial strain) Bulky products on equi for i al = favored. Disubsttuted cyclohexane s (anti) trans l product (syn) cis 2 products ( 2 up or 2 down) ( l up and i down) Boat conformation : unstable because of eclipse hydrogen and flagpole hydrogen due to. Interactions : unfavored interaction between methyl "s hydrogen with two axial hydrogens on same face . Bicyclic compounds : two rings share 2 or more common atoms . Count carbons left , right , up. Spiro cyclic : two rings with one common atom. Brett "s rule : bridgehead with small rings. Can not be part of double bond . ( (cid:12200) 7 c) steroche mistry of chemical reactions : Bhs sun - addition catalytic hudroge nation sun - addition. Oxymer curation anti (cid:15482: bra ( ( ( z t oh anti.

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