Lecture 332014.pdf

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Department
Chemistry
Course
CHEM 2332H
Professor
Christopher J.Douglas
Semester
Spring

Description
Lecture 332014Monday March 3 2014905 AMTodaySynthesis SolutionsAddition rxns to carbonyls2 mechanistic solutions2 group additions hydrates acetals cyanohydrins1 group additions Imines semicarbazonesAnother thing to think about besidesstepsamt yieldYield Monstersuppose we have red percentages of yield0909090906561nor do avg yieldavg per step Yield 066409 066 66The more steps you add the lower your product of decimals will beAlso consider the formation of byproducts isomers losses in each stepIf use less stuff then better for environment less stuff to have to dispose properlyless stuff to buy in the first placeHydroacylationnot ready for textbooks being worked onKey Mechanismsthis is hydrate formationCase 1 Strong acidweak nucleophile Ochem Page 1
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