Lecture 3282014.pdf

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Department
Chemistry
Course
CHEM 2332H
Professor
Christopher J.Douglas
Semester
Spring

Description
Lecture 3282014Friday March 28 2014905 AMTodayStaudinger LigationExam 2 NotesProblem SolvingSaxonBertozzi Science 2000 287 2007866 citationspretty significantPhosphinesAzides dont naturally occur in cellshard to see if things are in cells or where they are if theyre really smallBiomolecules can be modified w nonnatural funcitonal groups FGif original function is maintained you can use bioorthogonal its different but compatible unaffecting FG to do a reaction to modify groups in cellSince Staudinger Rxn uses water to free up phosphineoxideamine SaxonBertozzi used intermolecularity to link the 2 groups trap reactive nitrogen Ochem Page 1
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