CHEM 4701 Lecture Notes - Lecture 1: Opata Language, Bacteriophage, Vant (Band)
Document Summary
Breaking bond = incomplete, inelastic vibration kb = boltzman"s constant h = plank"s constnat. Inorganic chemistry page 1 usually do rxn in sol"n so limited by freezing and boiling pts of the solvent very accurate from slope get from y intercept very inaccurate but tells more info than delta. Inorganic chemistry page 2 can also do this in gas phase and look @ p every rxn step and rate constant has associated w/ it activation parameters. Variation of k w/ p --> volume of activation ideal gas volume of activation means you"re ordering things around b/c transition state takes less v than reactants --> associative mechanism. Ts takes more volume than reactants --> dissociative mechanism. Inorganic chemistry page 3 but not prefered to do in gas how does this all translate to dissociative/associative/interchange mechanism. X is the ligand being exchanged, l is some other ligand find rate law for apply steady state approx.
