CHM 1240 Lecture 23: Lecture_23Note_Mar_4_2020

Draw the structure of the MAJOR ORGANIC PRODUCT formed in each reaction. Show TEREOCHEMISTRY where it is essential. Assume the reactions have been terminated and neutralized a. 2-methylpropene Ha/Ni(EtOH-solvent b. (R)-1-bromo-2-butanol + Kl/(acetone-solvent)-→ c. (R)-3-bromo-2-hydroxypropanoic acid ZnH,O d. HyC-CH2-CH2-CN + NaCN .) high pressure e. NaOH + H3C-Cl --> f, trans-1-bromo-3-methylcyclobutane + Nal g. (R)-(+)-1-chloro-2-methylbutane + KOH h. t-butyl chloride xs H20> > → H3C H20 -> (H3C) C j, propyl chloride NaOEtEtOH (solvent)-- + k. HO-CH2-CHz-Br NaOH/H2O/(solvent)--→ [CMoj + H C-I l. H3C-C=CH NaNH2NH3 (liquid-solvent) + 5 m. HyC-Br NaO2C-CH3 (sodium acetate)