CHEM 2325 Chapter Notes - Chapter 15: Allyl Group, Ethylene, Alkene
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4 edensity y u bee areconcentrated a higherenergy ande repulsion. It h a q y thantibonding g inode. I j pka allylic position is only a propaneethane ethene so so o pkaan evenmore atterminalcarbons nan como lowestunoccupiedmo a reactive momo. Radical allylic halogenation contrastto radicalhalogenation s moreselective amate x initiatorpoor 17 or no eg 1. Snl wa cation intermediate a o canals x if. Ron hightempcona a or lowtempconditions cation stability secondaryprimary. Tbt ibnmobutzene ices 2 c c je p allylic a fit tertiaryallylic. Saz and sws allylicwaves aregreat electrophiles a na sus nai sus. Iya hydrogenate sosiccallmon gsqqnasnea. es su1kcalmoi terminal internal o energylessstable. 1 z pentadiene ann ye so s acailma conjugatedsystemsaremorestable. Broadas to 2 co g zaddition product terminalalkene. I me ocheat oenophile come s come ocheat lime cyclohexane pme me me y ideal scenario. I me slightlymoree rich butadienetendstoexistintrans conformation toreducestericstrain e emme badsteric i unreactive us s as ie itis.
