CHEM1100 Study Guide - Midterm Guide: Photon, Electron Affinity, Vsepr Theory

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23 Jun 2018
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Module 1 important concepts !
Atomic symbol
Z = atomic
number
A = mass number
X = atomic symbol
N = charge of the atom
Mass = protons + neutrons
History
Leucippus and Democritus (490 BC)!
introduced the idea that matter is made up of atoms, which are indivisible - the joint founders of
atomic theory. !
Leucippus stated that atoms are "imperceptible, individual particles that dier only in shape and
position”
The photoelectric eect
Researchers found that electrons could be knocked o a plate and onto a detector!
Dierent metals needed dierent wavelengths of light to get the electron to move !
Light (electromagnetic radiation) exhibits wave and particle properties !
Each particle of light is a “quanta” of energy which is a discrete set of energy!
Energy levels
electrons can absorb energy !
It also absorbs quantised values of energy !
The waves have to be a certain type of waves!
They have physical parameters they cannot cross !
Mass is defined by the International Prototype
Kilogram of platinum and iron. The error should
be zero but small changes are being found. !
Australia’s kilo is made of silicone. !
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Shielding and penetration
The eect of shielding and penetration is the following:!
The lewis structure
The lewis structure for organic compounds is drawn like this:!
!
Valence Shell Electron Pair Repulsion Theory (VSEPR)
The principle of minimising electron repulsion by placing electron pairs as far apart as possible. !
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Document Summary

The error should be zero but small changes are being found. Energy levels: electrons can absorb energy, it also absorbs quantised values of energy. The waves have to be a certain type of waves. The e ect of shielding and penetration is the following: The lewis structure for organic compounds is drawn like this: The principle of minimising electron repulsion by placing electron pairs as far apart as possible. Electron affinity is defined as the change in energy (in kj/mole) of a neutral atom (in the gaseous phase) when an electron is added to the atom to form a negative ion. The energy required to remove an electron completely from a species (in the gas phase) orbitals, subshells and principal shells. Things to remember: even though electrons reside in their own sub-shell, they can always accompany high sub-shells if excited.