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Final

How to do Error Analysis For labs and Final exam

4 Pages
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Department
Chemistry
Course Code
CHM242H5
Professor
Judith C Poe

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Combining errors in independent measurements.
Many experiments depend on several measured quantities, each of which has an
associated error. The rules for combining the errors are given below. These would not be
examined, but they can be used in your everyday work and will give you a feel for the
magnitudes involved and more importantly will train you in the quantitative assessment of error.
In all the following cases, the two independent measurements A and B with errors A and
B, are combined to give the quantity X which has the associated error X.
Errors in sums or differences:
The straightforward combination of individual errors in sums or differences gives an overall
error bound that is too pessimistic. It is unlikely that the individual errors will both be in the
same direction, though not of course impossible.
If X = A + B or X = A – B , then: X = {(A)2 + (B)2}
The expression is the same whether the quantities are added or subtracted. If more than two
quantities are involved the expression is simply extended in a similar fashion, that is if X = A +
B – C, then:
X = {(A)2 + (B)2 + (C)2}.
The resulting error is always larger than any of the individual errors, but not as large as their
sum.
If two values that are very similar are subtracted, the resulting error can be very large. Such
procedures are best avoided if at all possible – see example 2.
Example 1: In an experiment to determine the enthalpy of neutralisation of sodium hydroxide by
hydrochloric acid, the initial temperature was (19.2 ± 0.2) oC, and the final temperature (26.4 ±
0.2) oC. What is the temperature rise?
T = (T2 – T1) ± T
= (26.4 – 19.2) oC ± T
= 7.2 oC ± T.
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Description
Combining errors in independent measurements. Many experiments depend on several measured quantities, each of which has an associated error. The rules for combining the errors are given below. These would not be examined, but they can be used in your everyday work and will give you a feel for the magnitudes involved and more importantly will train you in the quantitative assessment of error. In all the following cases, the two independent measurements A and B with errors A and B, are combined to give the quantity X which has the associated error X. Errors in sums or differences: The straightforward combination of individual errors in sums or differences gives an overall error bound that is too pessimistic. It is unlikely that the individual errors will both be in the same direction, though not of course impossible. If X = A + B or X = A B , then: X = {(A) + (B) } 2 The expression is the same whether the quantities are added or subtracted. If more than two quantities are involved the expression is simply extended in a similar fashion, that is if X = A + B C, then: X = {(A) + (B) + (C) }. 2 The resulting error is always larger than any of the individual errors, but not as large as their sum. If two values that are very similar are subtracted, the resulting error can be very large. Such procedures are best avoided if at all possible see example 2. Example 1: In an experiment to determine the enthalpy of neutralisation of sodium hydroxide by hydrochloric acid, the initial temperature was (19.2 0.2) C, and the final temperature (26.4 o 0.2) C. What is the temperature rise? T = (T 2T ) 1 T = (26.4 19.2) C T o = 7.2 C T. www.notesolution.com
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