CHEM 2311 Midterm: CHEM 2311 GT Examp4iv

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15 Feb 2019
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E4 practice-iv (answers not provided: (32 points) circle the letter on the right that corresponds to the answer to each question. Roor: ro, br (iv) which of the following alcohols is most likely to undergo rearrangement during acid-promoted. Ff dehydration: 2,3-dimethyl-2-butanol n. 3,3-dimethyl-2-butanol, 3,3-dimethyl-1-butanol p. 4-methyl-2-pentanol (v) what is the major product of the following reaction, 3-methyl-2-butene, 2-metyl-3-butene, 2-ethyl-1-propene, 3-methyl-1-butene. Oms: carbocation, bromonium ion, radical, carbene (vii) what is class of product is formed from the reaction between 1-hexene and m-chloroperbenzoic acid, diol, primary alcohol. 4: (40 points) provide the structure of the major organic product obtained from the following reactions. Indicate the stereochemistry of the products wherever appropriate (and indicate if a mixture of isomers is formed). Dmf: (20 points) the following transformations cannot be performed in a single step. Provide sequences of reactions, showing reagents and isolated synthetic intermediates, to achieve each transformation. Problem solving hints: each of these transformations requires 2-3 steps.

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