CHE 321 Final: Final_Exam_Reaction_Sheet

• School: Stony Brook University
• Department: Chemistry
• Course: CHE 321
• Professor: grubbs

Document Summary

Todd"s che 321 final exam reaction sheet (c) copyright 2014 all rights reserved, created by todd rothman. 30 -> sn1: nabh4, bh3 / thf, h2o2 / oh- 1 mole hbr any halogen: nabh4, h, lialh4, h+ Major product can be the lower dergee any halogen rearangement you can only use hbr. Br goes to lower degree if mixed halogens (less. Z = oh, or, cl, br, i, coo. Reminder: h , d , t (syn) (syn) (syn) (syn) or ch2n2. Tbuo- or lda = hoffman other bases = zaitsev. Works with any type of alkyl halide (aldehyde or ketone) only 1r group adds on. Bases = nanh2 , nah, rmgbr, rli, - oh, -or, lda, nahco3 same r groups add on twice. Acids = h2so4 , h3o , nh4cl , hi, hbr. Nu = sh, cn, oh, ro, x, coo,c, nh2, n3. Sn2 = allyl > me > 1 > 2 never 3 or vinyl.