CHEM 241 Study Guide - Midterm Guide: Lithium Aluminium Hydride, Jones Oxidation, Thionyl Chloride
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Carboxylic acid to acid chloride (socl2, pyridine) Acid chloride reacted with h3o+ carboxylic acid. Acid chloride reacted with carboxylate and pyridine anhydride. Acid chloride reacted with roh ester. Acid chloride reacted with nh3 amine. Acid chloride reacted with gilman 1. ) (r)2culi 2. ) H2o (-78 c) r group replaces cl. H2o adds 1 oh and 2 h"s to where carbonyl was. Carboxylic acid to anhydride (acid chloride, pyridine) Anhydride reacted with h3o+ carboxylic acid. Ester reacted with h3o+ carboxylic acid. Ester reacted with roh, h+ replaces r group of ester with new r group, remains an ester. H2o adds oh and 2 r groups to where carbonyl was. )h2o adds 1 oh and 2 h"s to where carbonyl was. Ester reacted with naoh forms carboxylate. Amide reacted with h2o, h+, heat carboxylic acid. )h2o adds 1 nh2 and 2 h"s to where carbonyl was. Nitrile reacted with h2o, h+, heat carboxylic acid. )h2o replaces triple bond n with nh2.