CHM 113 Chapter Notes - Chapter 6: Calorimetry, Thermodynamics, Exothermic Process

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10 Apr 2014
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A property of a system that depends only on its present state. State functions do not depend on what has happened in the system, or what might happen in the system in the future. W = -pd v a. by a gas (through expansion) (1) d v is positive (2) w is negative a. to a gas (by compression) (1) (2) In systems at constant pressure, where the only work is pv, the change in enthalpy is due only to energy flow as heat (d h = heat of rxn: h = e + pv. D h is positive for endothermic rxns: calorimetry science of measuring heat, heat capacity (aka c) ratio of heat absorbed to increase in temperature a. D h = specific heat capacity x mass sol"n x increase in temp. 6. 3 hess"s law: statement of hess"s law.

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