CHEM 2261 Chapter : Notes2261Chapter6
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Compounds with an sp3 carbon bonded to a electronegative atom or group (e. g. as in alkyl halides) can undergo 2 types of reactions: substitution and/or elimination: The rate of a nucleophilic substitution reaction depends upon: (1) the structure of the alkyl halide (2) the leaving group (3) the nucleophile (4) the solvent. The rate of an sn2 reaction depends on the concentration of both the alkyl halide and the nucleophile, therefore it is a bimolecular reaction (second order). In an sn2 reaction the reactivity order of alkyl halides (due to steric effects) is: Sn2 reactions take place in a single step, without intermediates. The nucleophile attacks the substrate from a direction 180o away from the leaving group, causing inversion of configuration of the molecule. The leaving group in the sn2 reaction. The leaving ability of a group is a measure of its ease of displacement.
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