CHEM 20A Chapter Notes - Chapter 7: Van Der Waals Strain, Alkane, Ring Strain

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7. 1: petroleum originates from the deposition and decay of organic matter (of animal or vegetable origin) in oxygen-poor marine sediments, petroleu(cid:373)"s (cid:373)ajor (cid:272)o(cid:374)stitue(cid:374)ts are hydrocarbons compounds of carbon and hydrogen. This is a consequence of the increasing strength of dispersion forces between these molecules: mixtures of hydrocarbons such as petroleum do not boil at single, sharply defined temperatures. Such interactions are called steric strain, and they play a significant role in determining the structure of polyatomic molecules: consider the possibility that cyclohexane could have a planar hexagonal structure. Then each c-c-c bond angle would be 120 resulting in angle strain of 10. 5 . 7. 2. 3 branched-chain alkanes and isomerism: branched-chain alkane: a saturated hydrocarbon in which one or more carbon atoms are bonded to three or four other carbon atoms. The following set of rules is a part of that procedure: find the longest continuous chain of carbon atoms in the molecule.

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