CHEM 140C Chapter 24: CHEM 40C Beta Dicarbonyl compounds
15 Jan 2018
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T0 tl[oe+ a readily behaved stabilized nucleophile pdiester delocalized removal convert resonance by anions anion to of. H ( via condensation daisen by a single carbon which has between carbonyls. Etoti the#emptive # td@ny0hbmnnaieqfizakoch3ed3ylioetneidt3yifktttaaiseni. a e eoot =e!o t%o ek koet-ti i; + to . nudeophilic addition bhyctafrwgordaibff. Chfhoet sequence favored ketoester drives is an p strongly to acid . base vxn , with thermodynamic constant almost all endpoint product comes high equilibrium from this step elimination alkoxide. 17) ( 25) very ester little eno present but to proceed late enough xs. 3 in foresters that only d- k have one acidic hydrogen final bk next rxn norm. A . cannot esters mixture p - p - nuc dec w/ Crossed alleviated product to ester condensation claisen hvc elect ( no h "s condensation carbonyl. Ed gitto # neuttgefgoei. forming ymembered eieawpniieiosesor acidic hydrogens intra molecular.
