CHEM 121 Chapter Notes - Chapter 4: Bond-Dissociation Energy, Ionic Compound, Lattice Energy

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18 Nov 2016

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Ionic compounds are high-melting solids because of their ionic bonds. Lattice energy (is amount of energy that must be supplied to break an ionic solid into its individual gaseous ions and is thus measure of strength of solid"s ionic bonds) Molecular compounds are low-melting solids, liquids, or even gases. If attractive forces are stronger than repulsive forces, a covalent bond of formed, with 2 atoms held together and 2 shared electrons occupying region between nuclei. Chemical formula (lists symbols of compound"s constituent elements and uses subscripts to indicate number of atoms each element has) Structural formula (explicitly shows bonds between atoms between atoms and therefore gives much more information than just chemical equation) Bond dissociation energy (d) (amount of energy that must be supplied to break covalent bond between 2 atoms in an isolated molecule in gaseous state) *always positive because energy must always be added to break the bond*

Related Questions

Phase changes always associate with change of enthalpy. For the following situations, name the phase transition and indicate whether the process is exothermic or endothermic.

. Dry ice (solid carbon dioxide) turns to gaseous carbon dioxide. Answer:

. Water vapor turns to liquid water. Answer:

. Solid iron turns to liquid iron. Answer:

. Iodine vapor turns to solid iodine. Answer:

. Liquid helium turns to helium gas. Answer:

True or false

. Intermolecular forces are stronger than ionic and covalent bonds. Answer:

. For molecules with similar size and molar mass, those with higher polarity would have higher boiling point. Answer:

. Ion-dipole forces exist between ionic potassium bromide and polar water. Answer:

. Dispersion forces exist between argon and helium. Answer:

. Instantaneous dipoles exist in all molecules and atoms. Answer:

. The strength of dispersion forces depends on the molar mass but the shape of the molecules have no effect on dispersion forces. Answer:

. Ice has a higher density than water because ice has an ordered cagelike structure. Answer:

. Liquids with weaker intermolecular interactions have lower viscosity. Answer:

. Viscosity decreases with increasing temperature. Answer:

. For any molecules, the heat of vaporization is always lower than the heat of fusion because it takes more energy to make molecules to move past one another in a solid lattice. Answer:

* Circle the intermolecular force(s) that is/are present in each of the following species. [Hint: there may be more than one correct answer.]

Ar (hydrogen bonding, dipole-dipole forces, dispersion forces)

CH4 (hydrogen bonding, dipole-dipole forces, dispersion forces)

HBr (hydrogen bonding, dipole-dipole forces, dispersion forces)

HF (hydrogen bonding, dipole-dipole forces, dispersion forces)

CHCl3 (hydrogen bonding, dipole-dipole forces, dispersion forces)

* For the following pairs of atoms/molecules, circle the species that has the higher boiling point.

Ne or Xe

Cl2 or F2

HBr or HF

HCl or HI

H2O or H2S

* Phase changes always associate with change of enthalpy. For the following situations, name the phase

transition and indicate whether the process is exothermic or endothermic.

(a) Dry ice (solid carbon dioxide) turns to gaseous carbon dioxide.

Answer:

(b) Water vapor turns to liquid water.

Answer:

(d) Iodine vapor turns to solid iodine.

Answer:

(e) Liquid helium turns to helium gas.

Answer:

* True or false

1. Intermolecular forces are stronger than ionic and covalent bonds. Answer:

2. For molecules with similar size and molar mass, those with higher polarity would have higher boiling

point. Answer:

3. Ion-dipole forces exist between ionic potassium bromide and polar water.

Answer:

4. Dispersion forces exist between argon and helium. Answer:

5. Instantaneous dipoles exist in all molecules and atoms. Answer:

6. The strength of dispersion forces depends on the molar mass but the shape of the molecules have no effect on dispersion forces. Answer:

7. Ice has a higher density than water because ice has an ordered cagelike structure. Answer:

8. Liquids with weaker intermolecular interactions have lower viscosity. Answer:

9. Viscosity decreases with increasing temperature. Answer:

10. For any molecules, the heat of vaporization is always lower than the heat of fusion because it takes more energy to make molecules to move past one another in a solid lattice. Answer:

CHEM 121 Chapter Notes - Chapter 4: Bond-Dissociation Energy, Ionic Compound, Lattice Energy

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