CHEM237 Lecture Notes - Lecture 2: Imidazole, Hexane, Titration Curve

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First let"s examine the water molecule: the oxygen centre is surrounded by two nonbonding electrons, and two hydrogens. The hydrogens are 104. 5 degrees apart: the electronegativity of the oxygen atom creates a dipole in the water molecule. Furthermore water is able to hydrogen bond (n,o,f) with a nonbonding electron pair, and it is able to make four of them: this is the reason why water has different properties than ch4 (no n,o,f) and. Nh3 (can only have one hydrogen bond): with water, o-h is the donor and o is the acceptor, the bond length of this bond is 1. 8a. Hydrogen bonds are strongest when they are co-linear. We said before that water is able to make 4 hydrogen bonds each, so when we look at the structure of ice we can see the tetrahedral arrangement due to this ability to make 4 bonds. Thus, h bonds are important in ice and for liquid water as well.

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