CHM120H5 Lecture Notes - Lecture 16: Principal Quantum Number, Bohr Model, Pauli Exclusion Principle

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18 May 2015
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Bohr theory (1914) ran into problems when it was applied to atoms other than h, and was soon replaced by quantum mechanics (1926). When quantum mechanics was applied to the h atom, the same energies were calculated for the h atom energy levels as in the bohr model, For n = 1, 2, 3, (applies only to h atom!!) (1) but the method by which they were calculated was entirely different. Quantum mechanics assumes the electron is wave-like, and the planetary orbits of bohr theory (which views the electron as a particle) are discarded. Orbitals, which give us a picture of the most probable locations for the electron in a particular energy state, replace the bohr orbits. Since the electron is viewed as a wave, it is impossible to describe its precise location: an averaged picture is the best we can do!

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