CHM151Y1 Lecture 13: Lecture 13 Inorganic
Document Summary
Hybridization of b based compounds sp2 bybrids perpendicular to plane. High density source, release h to burn as demand of h needs. What happens lewis and base make such that substituents are large enough that they cannot get together sterically frustrated too large to form bond. Boron with phenyl groups around phosphate bulky ligand. No reaction when combined compounds too bulky add h split to make cation (r3ph) h+ on phosphorous, and (h-) on boron. Reversible metal free h2 activation similar to previous substitution bulky can see reaction. Other end like borane frustrated lewis pair both donor and acceptor in single molecule. Orange solution add h, ambient temperature, clears clear ass heat orange again capture and release h at will useful in current developments explain with lewis dot diagrams, vb theory. H2 of (# electrons in bonding orbital - # electrons in antibonding orbital) Build on that to address more complicated situation.
