CHEM 1A Lecture Notes - Lecture 29: Energy Conversion Efficiency, Gibbs Free Energy, Semipermeable Membrane

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6 Apr 2016
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The change in gibbs energy, g, is referred to as gibbs free energy because it deines the maximum energy produced in a chemical reacion that could be converted to work. Note that in reacions with a negaive entropy change, g is less negaive than h. This is because some heat must be released to the surroundings in order to compensate for the negaive s of the reacion, and thus cannot be converted to work. Note also that g is more negaive than h for reacions with a posiive entropy change: entropy (t s) can be converted into work. While it is possible to convert mechanical work into heat with 100% eiciency, the reverse is not possible. Due to the random moion of molecules in a body at a certain temperature, thermal energy is a low grade type of energy and cannot be eiciently converted into work.

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