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CHEM (30)
Joseph Piccirilli (9)

Class Notes for Joseph Piccirilli

Organic Chemistry III

Chemistry
CHEM 22200
Joseph Piccirilli
CHEM 22200 Lecture Notes - Lecture 10: Diazonium Compound, Sodium Nitrite, Phenyl Group
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Arenediazonium salts are stabilized by resonance Resonance structures stabilize the arenediazonium cation. N N N N N N N N arenediazonium salt alkyldiazonium salt Ar N NH H2O H2O 2 Ar N N R N NH 2 R N N harder to do compar...

Chemistry
CHEM 22200
Joseph Piccirilli
CHEM 22200 Lecture Notes - Lecture 6: Pi Bond, Sodium Hydroxide, Equilibrium Constant
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Handout 6: Enoates and Active Hydrogen Compounds (18) Chemistry 222 Organic Chemistry AcidBase Equilibria (Calculating Equilibrium Constants from pK s) a N C H + OH N C + H O 2 pK = 9 pK = 16 a1 a2 K = [H O2[ CN] [ OH][HC...

Chemistry
CHEM 22200
Joseph Piccirilli
CHEM 22200 Lecture Notes - Lecture 4: Acetic Acid, Benzene, Transesterification
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Handout 4Preparation of Carboxylic Acid Derivatives (Chapter 17) O O O O O O R H R R R OH R OR R NR 2 R Cl aldehyde ketone carboxylic ester amide acid chloride acid O O O carboxylic R C N acid derivatives R O R R SR [acyl ...

Chemistry
CHEM 22200
Joseph Piccirilli
CHEMК22200 Lecture 9: Handout 9(15)
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Haannddouutt 9: Thhee Gaabbrriel Syynttheessis, Diiazzottizattionn, andd thee Ma annniich Reeacctionn O Step 3 of Gabriel Synthesis O O N R NH2NH2 O N R NH + NH2R NHNH2 EtOH; reflux NH O O O O O O O H NH 2H2 N R NHR N R N ...

Chemistry
CHEM 22200
Joseph Piccirilli
CHEMК22200 Lecture 1: Handout 1(15)
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Chemistry 222Handout 1: Preparation and Reactions of Aldehydes and Ketones (Chapter 16) R bond; no geometric isomers C O 2 R sp2 C: 3sp + p O: 3sp + p Bond Bond Strength Bond Bond Strength Energy Lost Upon Going from C=Z t...

Chemistry
CHEM 22200
Joseph Piccirilli
CHEMК22200 Lecture 2: Handout 2(15)
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Handout 2Addition of Nucleophiles to the Carbonyl (Chapter 16) II. Addition of Alcohols O HO OC H + C2 5OH 2 5 (97 at CH 3 H (solvent) CH H equilibrium) 3 simple aldehydes form hemiacetals in alcohol; justas they form hydr...

Chemistry
CHEM 22200
Joseph Piccirilli
CHEM 22200 Lecture Notes - Lecture 8: Ketone, Electrophile, Enol
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O H c O O (1) NaOMeMeOH OCH 3 (2) H3O H a Hb O O Hc OCH 3 Ha H b O K =10 4 Ke A B eq q 10 9 C 04 + MeOH c O Hc q 1 O Hc O K e MeOH + OCH 3 OCH OCH 3 a 3 H b O H H O Ha O a b ketone a better electrophile than ester O OCH es...

Chemistry
CHEM 22200
Joseph Piccirilli
Inorganic Chemistry - Reference Guides

This Guide provides invaluable reference material to anyone who requires readily accessible information concerning the basic principles that underlie this complex science. The Guide carefully references the Periodic Table ...

Chemistry
CHEM 30100
All Professors
Permachart - Marketing Reference Guide: Iupac Nomenclature Of Inorganic Chemistry, Lithium Aluminium Hydride, Polyatomic Ion

p e r m a c h a rt s MT I n o r g a n i c C h e m i s t r y N o m e n c l a t u r e ...

Chemistry
CHEM 30100
All Professors
Permachart - Marketing Reference Guide: Locant, Parent Structure, Substituent

permacharts TM O r g a n icC h e m is t ryN o m e n c la t u r e Nam...

Chemistry
CHEM 22700
All Professors
Permachart - Marketing Reference Guide: Beta Particle, Beta Decay, Atomic Number

permacharts TM Periodic Table of the Elements ...

Chemistry
CHEM 11100
All Professors
Permachart - Marketing Reference Guide: Carnot Heat Engine, Carnot Cycle, Isentropic Process

permacha srtM PHYSICAL CHEMISTRY Basics Adiabatic process in which no heat is transferred into or out Internal energy The total kinetic and potent...

Chemistry
CHEM 11100
All Professors
Introductory Chemistry - Reference Guides

This Guide serves as a well organized and effective point of entry for anyone embarking upon the study of Chemistry. All fundamental terms are clearly organized in chart form, with illustrative graphics. More complex conce...

Chemistry
CHEM 11100
All Professors

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