CHEM 134 Lecture Notes - Lecture 18: Homologous Series, Substituent, Nsb Di 2

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The simplest saturated hydrocarbons are called alkanes. Methane, ch4, is the simplest alkane. The alkanes form a homologous series. Each member of the series differs by a specific number and kind of atoms. Choose the longest continuous chain of carbon atoms which gives the basic name or stem. 2 number each carbon atom in the basic chain, starting at the end that gives the lowest number to the first group attached to the main chain (substituent). 3 for each substituent on the chain, we indicate the position in the chain (by an arabic numeric prefix) and the kind of substituent (by its name). The position of a substituent on the chain is indicated by the lowest number possible. The number precedes the name of the substituent. 4 when there are two or more substituents of a given kind, use prefixes to indicate the number of substituents.

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