CHEM 2E03 Chapter Notes - Chapter 4: Heptane, Substituent, Cyclohexane

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15 Sep 2016
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Hydrocarbons that lack pi bonds are called saturated hydrocarbons or alkanes. Systematic names: names produced by iupac naming: identify the longest chain parent chain if there"s a competition of two chains of equal length, choose the chain with the greater number of substituents. Cyclo" indicates a ring in the alkane structure. When an alkyl group is connected to a ring, the ring is the parent when the ring has more carbons than the alkyl group. Always number the carbons on the substituents going away from the parent chain. Treat the complex substituent as if it"s a mini-parent with its own substituents. Place parenthesis around the name of a complex substituent. Isopropyl (1-metyhethyl): branched alkyl group with 3 carbon atoms, attached by the middle c. Location of a substituent group is identified with a number called a locant. If one substituent is present, it should be assigned the lowest possible #

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