1
answer
0
watching
2,224
views
11 Nov 2019
In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H bonds react at relative rates of 1:3.9:5.2 respectively. These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B, the A B product ratio will be 2. Consider chlorination of the alkane below at 35 °C. 1. Specify the most reactive C-H bond(s), a-c. Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, ie. a,c 2. Specify the site of chlorination in the major monochloro substitution product, a c s, a Retry Entire Group 5 more group attempts remaining Submit Answer
In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35 °C, primary, secondary, and tertiary C-H bonds react at relative rates of 1:3.9:5.2 respectively. These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, if A is formed twice as fast as B, the A B product ratio will be 2. Consider chlorination of the alkane below at 35 °C. 1. Specify the most reactive C-H bond(s), a-c. Two non-equivalent C-H bonds of comparable reactivity should be separated by commas, ie. a,c 2. Specify the site of chlorination in the major monochloro substitution product, a c s, a Retry Entire Group 5 more group attempts remaining Submit Answer
1
answer
0
watching
2,224
views
For unlimited access to Homework Help, a Homework+ subscription is required.
Nelly StrackeLv2
17 Sep 2019
Related textbook solutions
Basic Chemistry
5 Edition,
Timberlake
ISBN: 9780134138046
Principles of Chemistry Molecular Approach
4th Edition,
Tro
ISBN: 9780134112831
Principles of Chemistry Molecular Approach
3rd Edition, 2014
Tro
ISBN: 9780321971944
Chemistry: Structure and Properties
2nd Edition,
Tro
ISBN: 9780134293936
Chemistry: A Molecular Approach
3rd Edition,
Tro
ISBN: 9780321809247
Chemistry: A Molecular Approach
5th Edition,
Tro
ISBN: 9780134874371
Principles of Chemistry: A Molecular Approach
4th Edition,
Tro
ISBN: 9780134895741
Chemistry: The Central Science
14th Edition, 2017
Brown
ISBN: 9780134414232