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11 Nov 2019

At equilibrium, the concentrations of reactants and products can be predicted using the equilibrium constant, Kc , which is a mathematical expression based on the chemical equation. For example, in the reaction

aA+bB⇌cC+dD

where a , b , c , and d are the stoichiometric coefficients, the equilibrium constant is

Kc=[C]c[D]d[A]a[B]b

where [A] , [B] , [C] , and [D] are the equilibrium concentrations. If the reaction is not at equilibrium, the quantity can still be calculated, but it is called the reaction quotient, Qc , instead of the equilibrium constant, Kc .

Qc=[C]tc[D]td[A]ta[B]tb

where each concentration is measured at some arbitrary time t .

Part A

Part complete

A mixture initially contains A , B , and C in the following concentrations: [A] = 0.450 M , [B] = 0.850 M , and [C] = 0.300 M . The following reaction occurs and equilibrium is established:

A+2B⇌C

At equilibrium, [A] = 0.300 M and [C] = 0.450 M . Calculate the value of the equilibrium constant, Kc .

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Sixta Kovacek
Sixta KovacekLv2
1 Apr 2019

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