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17 Nov 2019
Reagents HBr HBr, H_2O_2, hv H_2O, H_2SO_4 Br_2 Cl_2 H_2, Pd Br_2. H_2O Cl_2, H_2O OsO_4 then NaHSO_3 Hg(OAc)_2, H_2O then NaBH_4 BH_3 then H_2O_2, NaOH O_3 then (CH_3)_2 S 2 equivalents of NaNH_2 H2, Lindlar's catalyst Na/NH_3 H_2SO_4, HgSO_4, (sia)_2BH then H_2O_2, NaOH 1 equivalent of NaNH_2 NBS, hv Br_2, hv Cl_2, hv HCl (CH_3)_3CO^-K^+ The above synthesis was designed using the Organic Chemistry Roadmaps in Appendix 11 of your textbook. In this synthesis, reagents from the table are used to carry out the indicated steps (shown in blue). In the box below, draw the structure of compound a You do not have to consider stereochemistry. If multiple constitutional isomers are formed, draw only the major product. Draw one structure per sketcher. Add additional sketchers using the dropdown menu in the bottom right corner. Separate structures with + signs from the dropdown menu.
Reagents HBr HBr, H_2O_2, hv H_2O, H_2SO_4 Br_2 Cl_2 H_2, Pd Br_2. H_2O Cl_2, H_2O OsO_4 then NaHSO_3 Hg(OAc)_2, H_2O then NaBH_4 BH_3 then H_2O_2, NaOH O_3 then (CH_3)_2 S 2 equivalents of NaNH_2 H2, Lindlar's catalyst Na/NH_3 H_2SO_4, HgSO_4, (sia)_2BH then H_2O_2, NaOH 1 equivalent of NaNH_2 NBS, hv Br_2, hv Cl_2, hv HCl (CH_3)_3CO^-K^+ The above synthesis was designed using the Organic Chemistry Roadmaps in Appendix 11 of your textbook. In this synthesis, reagents from the table are used to carry out the indicated steps (shown in blue). In the box below, draw the structure of compound a You do not have to consider stereochemistry. If multiple constitutional isomers are formed, draw only the major product. Draw one structure per sketcher. Add additional sketchers using the dropdown menu in the bottom right corner. Separate structures with + signs from the dropdown menu.
Tod ThielLv2
23 Jan 2019