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17 Nov 2019

Ionic Compound

Mass (g)

T i (Â°C )

Tf (Â°C)

âT (Â°C)

q (J)

âH (J/mol)

Calcium chloride

5g

22Â°C

34Â°C

+12Â°C

-251J

Ammonium nitrate

5g

22Â°C

16Â°C

-6Â°C

+125J

Magnesium Carbonate

2g

21Â°C

21Â°C

0Â°C

0

Sodium chloride

5g

21Â°C

20Â°C

-1

+21J

Cs (water) = 4.18 J/g-Â°C â¨, Density of water = 1g/mL â¨

Q) Calculate: âH (J/mol), for the four ionic compounds?

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1. Complete and balance the following chemical reaction: NH4NO3(s) + H2O(l) --> ?

Given

2. Volume of DI water used 50 mL

3. Mass of DI water 50 g

4. Initial temperature of water, Ti 22.5Â°C

5. Mass of NH4NO3 3.0 g

6. Moles of NH4NO3 ________0.0375__________mol

7. Final temperature of water, Tf 18.9Â°C

8. change in temperature of the water (?T) -3.6 Â°C

9. calculate the heat associate with water, qH2O ___ ___-752.4_____________ J

m*c* deltaT = (50g)(4.184 J/g*k)(-3.6) = -752.4

10. the heat either released or absorbed by the reaction (?Hrxn) ________+752.4____________ J

Question: [Please notice the units]

11. Calculate the change in enthalpy (?Hrxn) for this reaction. _____________ kJ ??

12. Calculate the heat of reaction in kJ per mole of NH4NO3 ______________ kJ/mol ??

13. If the heat capacity of the calorimeter was 25 J/oC, what would the new change in enthalpy (?Hrxn) for this reaction be? (Use equation 7 to recalculate the value from #10) ____________________ kJ/mol ?? [Equation 7: - q(rxn) = q(soln) + q(calorimeter)

14. Is this an exo- or endothermic reaction? Explain the reasoning behind your choice. ??

15. Calculate the change in enthalpy for the reaction (?Hrxn) per mole using equation 8 and Table 2. NH4NO3 (s) --> NH4NO3 (aq)

__________________kJ/mol ?? [Equation 8: ?H_rxn = sum{ n?H_f (products) - sum{ n?H_f (reactants)

16. What is the percent error between your value and the value calculated from 13? What are some possible sources of error in the experiment?

__________________% error

Please answer to the best of your ability

Show transcribed image text correctly.Completion and turning in of the entire review will result in an additional +3 pts on your final exam. Show all work to get extra credit. Please contact your instructor for clarification or specific questions. Report the following answers to the following problems with the correct number of significant figures and units: 1. 1 (0521 g 0.4953 0098 61â-24.135ë¯¸+1(120 64 g 4.1847 a)(21st-241530 1 (98.61 C-24.135)120.64g 4.1 21.5Â°C-24.153C) 0.0213548 moles b. (00020334-ern) + ((61210 goles Og) 0.002030 moles 1.02 moles (68.79 mlt29.901 ml) (26.3-0.230) c. 2. You are drying a sample of Bas(POsh. After 5 minutes of drying it weighs 1.2034 g. You continue to dry the sample for another 5 minutes and it now weighs 1.9346 g. What is the percent change in mass? 3. What is the percent mass of carbon in sodium carbonate? 4. What is the density of water at 23.1051Â°c? Use Table 1.1 on page 27 of your lab manual to help. 5. Based on the following reacts, predict the products. Write the balanced molecular equation, total ionic equation, and net ionic equation. All reactions are done in water a. Sodium chloride +silver (I) nitrate b. Calcium bromide + iron (III) sulfate c. Ammonium phosphate+ nickel (II) nitrate d. Hydrochloric acid+ calcium carbonate 6. Write the two balanced chemical reactions for a. Copper (II) oxide reacting with methane under high heat b. Copper (1) oxide reacting with methane under high heat 7. You analyze a mixed sample of copper (1) oxide and copper (II) oxide. The plot and trendline for mass of copper versus mass of mixture yields a slope of 0.8031. What are the mass percents of copper (0) oxide and copper (II) oxide in the mixture?
8. During week 1 of the Empirical Formula Lab you extinguished your "L-tube" flame without waiting 9. 20.00 ml of a 0.30 M potassium phosphate solution is combined with 20.00 mL of a 0.40 M solution 10. An Erlenmeyer flask is capped with a rubber stopper at room temperature (25 C) and atmospheric 11. The first step of the copper cycle lab was reacting solid copper with nitric acid. The copper ends up 12. What are the spectator ions in the 6 reactions performed during the copper cycle lab? for the reaction to cool and did NOT relight the "L-tube" flame. How would this affect your calculated percent mass compared to the true percent mass? of calcium chloride. What is the limiting reactant? What is the identity of the precipitate formed in the reaction? How many grams of product should be collected? pressure (1 atm). What temperature does the Erlenmeyer flask need to be heated to for the stopper to pop off? Assume it needs to exceed external pressure by 0.5 atm to release the stopper. oxidizing to copper (ll). What is the oxidizing reagent in this reaction? 13. The known specific heat capacity of aluminum is o g mo 25.316 g of aluminum is placed in 99.134 of water at a starting temperature of 22.45Â°C. The metal has a AT-84.02c what is the final 14. The AH, of cobalt (U) nitrate is +47.7 kJ/mol. What is the AHr of solid cobalt (1) nitrate? 15. 5.000 g of aluminum (Il) chloride is dissolved in 60.0 mL of water. The temperature changes by 16. Draw the Lewis dot symbols for the following atoms: temperature of the water? ÎÎ(Nouql)--205.00 kJ/mol ÎÎ,(Co2"m)--58.2 kJ/mol 0.331 Â°C. The specific heat capacity of aluminum (III) chloride is 0.903 Wat s AH.? what is ÎÎ a Ð°, Ð½Ðµ Ñ, Ñ c. Ar d. P e. H 17. Draw the Lewis structures for the following molecules: a. NHa b. O2 XeF d. NF

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Ionic Compound	Mass (g)	T i (Â°C )	Tf (Â°C)	âT (Â°C)	q (J)	âH (J/mol)
Calcium chloride	5g	22Â°C	34Â°C	+12Â°C	-251J
Ammonium nitrate	5g	22Â°C	16Â°C	-6Â°C	+125J
Magnesium Carbonate	2g	21Â°C	21Â°C	0Â°C	0
Sodium chloride	5g	21Â°C	20Â°C	-1	+21J