Question

I need #2, 4 problems help! The only hit i got from #2 is as follows:

The reactivity rate can be explained by stability of radical strucures of respective products in the table. Normally the stability of Carbon radicals follows as given below: tertiary > secondary > primary > methyl

I need cacluation using table 6.2

GAS-PHASE RLJ 6. 248 relationship ap- 2. Use the constants for the reactions proach to calculate the rate calculate t of OH with the following compounds and in percentage difference from the recommended values Table 6.2: ethane (b) n-butane, (c) 2-methylpen- tane, (d) (a) (e) 2,2,3-trimethyl butane, (f n-nonane, (g) n-decane approach the relationship to calculate the rate constants for the reactions of NO with the following compounds and calculate the per- centage difference from the recommended values in Table 6.3: (a) n-butane, (b) 2-methylbutane, (c) n- hexane, (d) 2,3-dimethylbutane, (e) n-octane, (f n-non 4. Two of the products of the OH reaction with limonene that have been observed are the following: CHO Show mechanisms that would form these products. 5. 2 reaction is not quite the high pressure limit at 1 atm. The occurs by addition of the oH to the triple h the reaction at 300 K, ko 50 cule