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18 Nov 2019
2. Write the structure of the major organic product expected from each of the following reactions. (108 pts) (a) 1-butanol + PBr3 (b) 2-methylpropane Br2+light (c) 1-bromo-3,3-dimethylbutane + potassium tert-butoxide + tert-butyl alcohol+heat (d) tert-butyl chloride +sodium ethoxide (CH3CH2ONa) + ethanol (e) 1-pentene + HCl (f) 2-methyl-2-butene + HBr in the presence of 1% peroxide (ROOR) (g) 3,3-dimethyl-2-butanol + H2SO4 +heat (h) cyclohexene + Br2 (i) 1,2-dimethylcyclohexene + H2+ Pt catalyst
2. Write the structure of the major organic product expected from each of the following reactions. (108 pts) (a) 1-butanol + PBr3 (b) 2-methylpropane Br2+light (c) 1-bromo-3,3-dimethylbutane + potassium tert-butoxide + tert-butyl alcohol+heat (d) tert-butyl chloride +sodium ethoxide (CH3CH2ONa) + ethanol (e) 1-pentene + HCl (f) 2-methyl-2-butene + HBr in the presence of 1% peroxide (ROOR) (g) 3,3-dimethyl-2-butanol + H2SO4 +heat (h) cyclohexene + Br2 (i) 1,2-dimethylcyclohexene + H2+ Pt catalyst
Collen VonLv2
2 Nov 2019