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23 Nov 2019
The two-step mechanism shown below has been proposed for thereaction of nitric oxide with bromine:
Step 1: NO(g) + Br2(g) â NOBr2(g)
Step 2: NOBr2(g) + NO(g) â 2 NOBr(g)
a) What is the overall (net) reaction?
b) What is the role of NOBr2 in this reaction? Explainbriefly.
c) What is the predicted rate law if the first step is much slowerthan the second step? Explain.
d) If the observed rate law is rate = k [NO]2 [Br2],what can you conclude about the ratedetermining step? Explain.
The two-step mechanism shown below has been proposed for thereaction of nitric oxide with bromine:
Step 1: NO(g) + Br2(g) â NOBr2(g)
Step 2: NOBr2(g) + NO(g) â 2 NOBr(g)
a) What is the overall (net) reaction?
b) What is the role of NOBr2 in this reaction? Explainbriefly.
c) What is the predicted rate law if the first step is much slowerthan the second step? Explain.
d) If the observed rate law is rate = k [NO]2 [Br2],what can you conclude about the ratedetermining step? Explain.
Lelia LubowitzLv2
9 Sep 2019