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the following mechanisim for decompostion of ozone in theatmosphere
O3-----> O2+O and its reverse(k1,kz')
O+ O3----> O2+O2 (k2, the reserve rxn is nigligibly slow)
use steadt-state with O treated as an intermediate, to find therate of decompostion of O3, show that step 2 is slow, then the rateis second order in O3 and -1 in O2
the following mechanisim for decompostion of ozone in theatmosphere
O3-----> O2+O and its reverse(k1,kz')
O+ O3----> O2+O2 (k2, the reserve rxn is nigligibly slow)
use steadt-state with O treated as an intermediate, to find therate of decompostion of O3, show that step 2 is slow, then the rateis second order in O3 and -1 in O2
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Irving HeathcoteLv2
4 Oct 2019
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