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27 Nov 2019

One mole of a monoatomic ideal gas expands adiabatically from T= 298.15 K and P = 1 bar against a constant external pressure of0.75 bar. Find the final temperature of the gas, the molar workdone, and the change in the molar entropy for this process.

I understand the process is an irreversible adiabatic so I cannotuse PVδ=Constant

I Know:

q=0

ΔU=w=Cv(T2-T1)

w(irreversible)= -PextΔV

so, CvΔT=-PextΔV

Cv=3/2R, PV=nRT

Therefore : 3/2(R)(T2-T1) =-Pext{(RT2/Pext)-(RT1/P)}

I do not know how to solve forT2

I can finish the rest of the problem if someone could pleaseexplain (step-by-step) how to solve for T2

Any help would be greatly appreciated.

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Hubert Koch
Hubert KochLv2
7 Nov 2019

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