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The thermodynamic properties for areaction are related by the equation that defines the standard freeenergy, ?G?, in kJ/mol:?G?=?H??T?S?
where ?H? is the standard enthalpy changein kJ/moland ?S? is the standard entropy changein J/(mol?K). A good approximation of the free energychange at other temperatures, ?GT, can also beobtained by utilizing this equation and assuming enthalpy(?H?) and entropy (?S?) change little withtemperature. ****PartA For the decomposition of calciumcarbonate, consider the following thermodynamic data: ?H?rxn 178.5kJ/mol ?S?rxn 161.0J/(mol?K)
Calculate the temperature in kelvins above which this reaction isspontaneous. Express your answer to foursignificant figures and include the appropriate units. The standard free energy change,?G?, and the equilibrium constantK for a reaction can be related by the followingequation:?G?=?RTlnK
where T is the Kelvin temperature and R is equal to 8.314 J/(mol?K). ****PartB Calculate the equilibrium constant forthe following reaction at room temperature, 25 ?C:CaCO3(s)?CaO(s)+CO2(g)
Express your answernumerically to three significant figures.
****PART A (Unrelated) The normalboiling point of Br2(l) is 58.8 ?C, andits molar enthalpy of vaporization is ?Hvap= 29.6 kJ/mol. Calculatethe value of ?Swhen 1.70molof Br2(l) is vaporized at 58.8 ?C.
The thermodynamic properties for areaction are related by the equation that defines the standard freeenergy, ?G?, in kJ/mol:
?G?=?H??T?S?
where ?H? is the standard enthalpy changein kJ/moland ?S? is the standard entropy changein J/(mol?K). A good approximation of the free energychange at other temperatures, ?GT, can also beobtained by utilizing this equation and assuming enthalpy(?H?) and entropy (?S?) change little withtemperature.****PartA
For the decomposition of calciumcarbonate, consider the following thermodynamic data:
Calculate the temperature in kelvins above which this reaction isspontaneous.
?H?rxn | 178.5kJ/mol |
?S?rxn | 161.0J/(mol?K) |
Express your answer to foursignificant figures and include the appropriate units.
The standard free energy change,?G?, and the equilibrium constantK for a reaction can be related by the followingequation:
?G?=?RTlnK
where T is the Kelvin temperature and R is equal to 8.314 J/(mol?K).****PartB
Calculate the equilibrium constant forthe following reaction at room temperature, 25 ?C:
CaCO3(s)?CaO(s)+CO2(g)
Express your answernumerically to three significant figures.
****PART A (Unrelated)
The normalboiling point of Br2(l) is 58.8 ?C, andits molar enthalpy of vaporization is ?Hvap= 29.6 kJ/mol.
Calculatethe value of ?Swhen 1.70molof Br2(l) is vaporized at 58.8 ?C.
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Elin HesselLv2
17 Dec 2019
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