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11 Dec 2019

Verifying the moles and mass of C6O6H8 from KIO3 titration and determing average % of vitamin C.

Experiment: Measured 50.0 mL of apple juice in an erlenmeyer flask. Add 1g KI and 5mL of 1 M HCI to the mixture. Add 2-3 mL of 0.5% starch solution. Titrate with 0.0100 M KIO3 through a burrette. Repeat 3 times.

Results:

Juice 1 Juice 2 Juice 3
Juice Volume (mL) 50.0 50.0 50.0
mL of KIO3dispensed (mL) 5.15 5.92 4.98
moles of IO3-
moles of C6O6H8
Mass of C6O6H8 (mg)
Male % Vitamin C
Female % Vitamin C

What I have tried:

To find the number of IO3- moles:

[(mL of KIO3 dispensed) * (0.001)] * (0.0100 M KIO3) = moles IO3-

To find the number of C6O6H8 moles:

[(mL of KIO3 dispensed) * (0.001)] * (0.0100 M KIO3) *3 = moles C6O6H8

To find the mass of C6O6H8:

([(mL of KIO3 dispensed) * (0.001)] * (0.0100 M KIO3) *3) * 176.124 mol C6O6H8 = mass of C6O6H8 (then convert to mg)

When I do this I get the following masses for C6O6H8:

Juice 1 Juice 2 Juice 3
27.057 mg 31.280 mg 26.312 mg

The issue I'm having when calculating the mass of vitamin C in a single serving (240 mL) for each titration.

I'm assuming since 240/50 = 4.8, you would multiply the mass of C6O6H8 by 4.8 for each titration. But I'm getting really big numbers when doing this. And the reason I'm would like help or clarification is because the next question states:

"The % Vitamin C is based on the recommended daily allowance which is 75 mg for females and 90 mg for males. Calculate the % of vitamin C based on your results from the mass of vitamin in a single serving (240mL) for the average male and average female"

But if 240 mL has 120% of the daily recommended allowance of Vitamin C, then 240 mL of apple juice should contain between 90 mg to 108 mg of Vitamin C which is much less than the results I am getting. I am not sure if I am reading the question wrong or if my calculations are wrong. Any help and explanations would be appreciated. Thank you!

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