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11 Dec 2019

The borate ion, [B4O5(OH)4]2-, present in 4.0 mL of a saturated Na2[B4O5(OH)4]·8H2O solution at 48.0 C is diluted to 30.0mL with warm DI water. The resulting solution was titrated to the bromoceresol green endpoint with 20.00mL of 0.250 M HCl.

How many moles of [B4O5(OH)4]2- are present in the sample?

What is the molar solubility of [B4O5(OH)4]2- in the sample?

What is the Ksp of Na2[B4O5(OH)4] from the information above?

Calculate the free energy change for the dissolution of Na2[B4O5(OH)4]·8H2O at given temperature.

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