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13 Dec 2019

The equilibrium constant for the esterification of ethanol and aceticacid in an aqueous solution CH3COOH(aq) + C2H5OH(aq) -----> CH3COOC2H5(aq) + H2O(l) amounts to 0.566 at 298 K. The reaction mixture initially contains 0.040 mol dm^−3 of acetic acid and 0.025 mol dm^−3 of ethanol. Find themolar concentration of ethyl acetate at the equilibrium. Assume that the pH is low enough that CH3COOH is not dissociated at all and thatthe activity of water equals 1 just like for pure liquid water (after all,the solution is quite dilute). Hint:This problem requires you to keep an extra large number ofsignificant digits in all intermediate calculations: otherwise, your finalanswer will be very inaccurate. Do not forget to check your answer in the end.

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Casey Durgan
Casey DurganLv2
17 Dec 2019

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