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18 Dec 2019

1. A particular reaction has a ΔHo value of -100 kJ and ΔSo of -297 J/mol K at 298 K. Assuming that ΔHo and ΔSo hardly change with temperature, determine the temperature in oC at which the spontaneity of this reaction changes.

2.Given the following data,

4 Al(s) + 3 O2(g) => 2 Al2O3(s) ΔGo = -3,352

4 Al(s) + 3 MnO2(s) => 3 Mn(s) + 2 Al2O3(s) ΔGo = -1,794

Determine ΔGfo for MnO2(s)

3. At 270 K, ΔGo equals -44 kJ for the reaction, Cl2(g) + Br2(g) <=> 2 BrCl(g)

Calculate the value of ln K for the reaction at this temperature to one decimal place.

4. At a certain temperature, 310 K, Kp for the reaction,
F2(g) <=> 2 F(g), is 6.8 x 1018.
Calculate the value of DGo in kJ for the reaction at this temperature.

5. The value of ΔGo for the reaction, N2(g) + 3 H2(g) <=> 2 NH3(g) is -32.90 kJ at 298 K.

Calculate the value of ΔG in kJ at 298 K if the partial pressures of N2, H2 and NH3 are 8.553, 8.881, and 63 atm respectively.

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Elin Hessel
Elin HesselLv2
31 Dec 2019

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