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18 Dec 2019

NMR (nuclear magnetic resonance) Uses the same theory and technology as an MRI!

1-What is the source of energy in NMR?____________________________________ What happens to atoms in a molecule exposed to this energy?_______________________________

2-What are two atom types that can be observed by NMR?________________________

3-What units are used to measure the strength of the magnetic field used?____________________ More significantly for us, what units are used to indicate the frequency of radiation used for resonance?________________

(Our instrument downstairs (a picoSpin) is 45 MHz. At the MN NMR Center at the U, they have instruments ranging 500 – 900 MHz.)

4-What can be distinguished with NMR?______________________________________________________

5-What are the axes of an NMR spectrum?____________________________________________________

6-What are the four different features of a spectrum that can provide information?

7-The number of NMR signals in a spectrum is equal to what?___________________________________

8-The position of an NMR signal in a spectrum depends on the electronic environment surrounding a particular __________________________.

9-If a proton is attached to an electronegative atom, it absorbs (downfield or upfield).

10-Where in an NMR spectrum would we expect to see an aldehyde H? See Table 14.1 ________________

11-What information is given by the area under an NMR signal?____________________________________

12-What information about is given by spin-spin splitting?________________________________________

13-How many peaks are contained in an NMR signal that has been described as a triplet?_________________________ How many adjacent protons are splitting this signal?________________

Skipping to section 14.11…

14-What do the number of different signals in a 13C spectrum indicate? __________________________________

15-What is the range of chemical shifts in a 13C spectrum?______________________________________________

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Jean Keeling
Jean KeelingLv2
31 Dec 2019

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