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18 Dec 2019

A. In any solution of HCl in water we’d expect to find not only H+ but also Cl– What concentration of Cl– would you expect to observe in a solution of HCl with an initial concentration of 1.00 x 10–8 M in water?

B. In a solution containing water as the solvent we’d also expect to find some concentration of OH–. Write a mathematical expression that would permit you to calculate [OH–] if you knew [H+].

C. If you were to handle a bottle containing an HCl solution in water that was initially 1.00 x 10–8 M it is unlikely that you would get an electrical shock from it, so it must be that the number of positive ions in the bottle exactly equals the number of negative ions. So write a mathematical expression representing this equality that takes into account all the ions present in a 1.00 x 10–8 M solution of HCl in water. You obtained a value for [Cl–] and an expression for [OH–] above, so plug those in and solve for [H+]. What result does this approach give for the pH of a 1.00 x 10–8 M HCl solution in water? Does this value seem more reasonable than that which you obtained in Key Question 3? If so, in what way is it more reasonable?

1. Use the approach in Key Questions (A–C) to calculate the pH of a solution of HCl in water that’s initially 1.00 x 10–3 M. Is the result reasonable based on your chemical intuition?

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Beverley Smith
Beverley SmithLv2
31 Dec 2019

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