Write equations for the reaction of 1-butanol with each reagent. Where you predict no reaction, write NR.
(a) Na metal
(b) HBr, heat
(c) HI, heat
(d) PBr3
(e) SOCl2, pyridine
(f) K2Cr2O7, H2SO4, H2O, heat
(g) HIO4
(h) PCC
(i) CH3SO2Cl, pyridine
(j) CO2Cl2 and DMSO, followed by triethylamin
(k) DMP
(l) triethylamine
Write equations for the reaction of 1-butanol with each reagent. Where you predict no reaction, write NR.
(a) Na metal (b) HBr, heat |
(c) HI, heat (d) PBr3 |
(e) SOCl2, pyridine (f) K2Cr2O7, H2SO4, H2O, heat |
(g) HIO4 (h) PCC |
(i) CH3SO2Cl, pyridine (j) CO2Cl2 and DMSO, followed by triethylamin |
(k) DMP (l) triethylamine |
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Related questions
From the choices provided below, list the reagent(s) in orderthat will react with 1-butanol to form butanoic acid. (Specify thereagents you would use to carry out the conversion by using lettersfrom the table. The reaction may require more than one step, if so,write the letters in the order that they are used, e.g., abc. Nomore than four steps are required for this synthesis. If two ormore ways of conversion to the same product are possible, show onlyone of them.)
Reagents available | ||
---|---|---|
a. Br2, CCl4 | f. NaNH2 (3 equivalents) | k. NH3 |
b. HS?Na+, H2O | g. H2O | l. SOCl2, pyridine |
c. H3PO4, heat | h. H2SO4, H2O | m. OsO4 / H2O2 |
d. Cl2 / H2O | i. HBr, heat | n. pyridinium chlorochromate (PCC) |
e. K2Cr2O7, H2SO4, H2O, heat | j. RCO3H |