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The most stable form of glucose (blood sugar) is a six-membered ring chair conformer with its five substituents all in equatorial positions. Draw the most stable form of glucose by putting the OH groups on the appropriate bonds in the chair conformer.

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1. Draw trans-1,4-di-t-butylcyclohexane (ONLY chair conformer but draw however you wish). Label the branches as axial or equatorial. Are the branches eclipsed, staggered, or anti? REPEAT for the "ring flip" (other chair conformer). Which conformer has the lower energy (or is there only one conformer)?2. For each central atom, give its hybridization and 3-D geometry. a) HCCH b)HCO2H c)CH3NH23. Give the bond type. When appropriate show the "tiny" charge or full charge. a)HCOOH C O is________& O H is________ b)in NaOCH2CH3 Na O is________ & C O is________ & CH is________4. For ONE sigma bond vs ONE aliphatic pi bond, compare: a)the number of electrons in the bond b)the location of the electrons in the bond (relative to the inter nuclear axis) c) how does the location of the electrons affect whether the bond is free to rotate or is stiff d)how the location of the electrons affect the ease of reagents getting near enough to reach (ease of breaking the bond)

The cyclohexane derivative shown exists primarily in the morestable of the two available chair conformations. Give the position,axial or equatorial, of each of the three groups shown in the morestable chair conformation. If a group divides its time equallybetween axial and equatorial positions, indicate this withax/eq.

The table of "Axial Strain Energies for MonosubstitutedCyclohexanes" found in the "Strain Energy Increments" section ofthe Reference tool is useful for answering thisquestion.

The choices are axial, equatorial, orboth.

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The most stable form of glucose (blood sugar) is a six-membered ring chair conformer with its five substituents all in equatorial positions. Draw the most stable form of glucose by putting the OH groups on the appropriate bonds in the chair conformer.

glucose

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The most stable form of glucose (blood sugar) is a six-membered ring chair conformer with its five substituents all in equatorial positions. Draw the most stable form of glucose by putting the OH groups on the appropriate bonds in the chair conformer. glucose

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Related textbook solutions

Basic Chemistry

Principles of Chemistry Molecular Approach

Principles of Chemistry Molecular Approach

Chemistry: Structure and Properties

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The most stable form of glucose (blood sugar) is a six-membered ring chair conformer with its five substituents all in equatorial positions. Draw the most stable form of glucose by putting the OH groups on the appropriate bonds in the chair conformer.

glucose